Webb Peers Into Frozen Heart of Molecular Cloud – Unveils Dark Side of Pre-Stellar Ice Chemistry
An international team of astronomers has reported the discovery of diverse ices in the darkest regions of a cold molecular cloud measured to date by studying this region. This result allows astronomers to examine the simple icy molecules that will be incorporated into future exoplanets, while opening a new window on the origin of more complex molecules that are the first step in the creation of the building blocks of life. Credit: Image: NASA, ESA, CSA, Science: Fengwu Sun (Steward Observatory), Zak Smith (The Open University), IceAge ERS Team, Image Processing: M. Zamani (ESA/Webb)
Webb has identified frozen forms of a wide range of molecules, including carbon dioxide, ammonia, and methane.
The discovery of diverse ices in the darkest regions of a cold molecular cloud measured to date has been announced by an international team of astronomers using 
This image by NASA’s James Webb Space Telescope’s Near-Infrared Camera (NIRCam) features the central region of the Chamaeleon I dark molecular cloud, which resides 630 light years away. The cold, wispy cloud material (blue, center) is illuminated in the infrared by the glow of the young, outflowing protostar Ced 110 IRS 4 (orange, upper left). The light from numerous background stars, seen as orange dots behind the cloud, can be used to detect ices in the cloud, which absorb the starlight passing through them. Credit: Image: NASA, ESA, CSA, Science: Fengwu Sun (Steward Observatory), Zak Smith (The Open University), IceAge ERS Team, Image Processing: M. Zamani (ESA/Webb)
James Webb Space Telescope Unveils Dark Side of Pre-stellar Ice Chemistry
If you want to build a habitable planet, ices are a vital ingredient because they are the main source of several key elements — namely carbon, hydrogen, oxygen, nitrogen, and sulfur (referred to here as CHONS). These elements are important ingredients in both planetary atmospheres and molecules like sugars, alcohols, and simple 
An annotated version of the image above. The two background stars used in this study, NIR38 and J110621 are denoted on the image in white. Credit: NASA, ESA, CSA, and M. Zamani (ESA/Webb); Science: F. Sun (Steward Observatory), Z. Smith (Open University), and the Ice Age ERS Team
In addition to the identified molecules, the team found evidence for molecules more complex than methanol, and, although they didn’t definitively attribute these signals to specific molecules, this proves for the first time that complex molecules form in the icy depths of molecular clouds before stars are born.
“Our identification of complex organic molecules, like methanol and potentially ethanol, also suggests that the many star and planetary systems developing in this particular cloud will inherit molecules in a fairly advanced chemical state,” added Will Rocha, an astronomer at Leiden Observatory who contributed to this discovery. “This could mean that the presence of precursors to prebiotic molecules in planetary systems is a common result of star formation, rather than a unique feature of our own solar system.”
By detecting the sulfur-bearing ice carbonyl sulfide, the researchers were able to estimate the amount of sulfur embedded in icy pre-stellar dust grains for the first time. While the amount measured is larger than previously observed, it is still less than the total amount expected to be present in this cloud, based on its density. This is true for the other CHONS elements as well. A key challenge for astronomers is understanding where these elements are hiding: in ices, soot-like materials, or rocks. The amount of CHONS in each type of material determines how much of these elements end up in 
Astronomers have taken an inventory of the most deeply embedded ices in a cold molecular cloud to date. They used light from a background star, named NIR38, to illuminate the dark cloud called Chamaeleon I. Ices within the cloud absorbed certain wavelengths of infrared light, leaving spectral fingerprints called absorption lines. These lines indicate which substances are present within the molecular cloud.
These graphs show spectral data from three of the James Webb Space Telescope’s instruments. In addition to simple ices like water, the science team was able to identify frozen forms of a wide range of molecules, from carbon dioxide, ammonia, and methane, to the simplest complex organic molecule, methanol.
In addition to the identified molecules, the team found evidence for molecules more complex than methanol (indicated in the lower-right panel). Although they didn’t definitively attribute these signals to specific molecules, this proves for the first time that complex molecules form in the icy depths of molecular clouds before stars are born.
The upper panels and lower-left panel all show the background star’s brightness versus wavelength. A lower brightness indicates absorption by ices and other materials in the molecular cloud. The lower-right panel displays the optical depth, which is essentially a logarithmic measure of how much light from the background star gets absorbed by the ices in the cloud. It is used to highlight weaker spectral features of less abundant varieties of ice.
Credit: Illustration: NASA, ESA, CSA, Joseph Olmsted (STScI), Science: Klaus Pontoppidan (STScI), Nicolas M. Crouzet (LEI), Zak Smith (The Open University), Melissa McClure (Leiden Observatory)